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    <title>UTas ePrints - Trace-element signatures of apatites in granitoids from the Mt Isa Inlier, northwestern Queensland</title>
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    <meta content="Belousova, E.A." name="eprints.creators_name" />
<meta content="Walters, S.G." name="eprints.creators_name" />
<meta content="Griffin, W.L." name="eprints.creators_name" />
<meta content="O'Reilly, S.Y." name="eprints.creators_name" />
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<meta content="Trace-element signatures of apatites in granitoids from
the Mt Isa Inlier, northwestern Queensland" name="eprints.title" />
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<meta content="260100" name="eprints.subjects" />
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<meta content="apatite, granitoid, indicator minerals, mineralisation, Mt Isa Inlier, trace elements." name="eprints.keywords" />
<meta content="The concentrations of trace elements in apatite from granitoid rocks of the Mt Isa Inlier have been investigated using the laser-ablation inductively coupled plasma-mass spectrometry (ICP-MS) microprobe.
The results indicate that the distribution of trace elements [especially rare-earth elements (REE), Sr, Y, Mn and Th] in apatite strongly reflects the chemical characteristics of the parental rock. The variations in the trace-element concentrations of apatite are correlated with parameters such as the SiO2 content, oxidation state of iron, total alkalis and the aluminium saturation index (ASI). The relative enrichment of Y, HREE and Mn and the relative depletion of Sr in the apatites studied reflect
the degree of fractionation of the host granite. Apatites from strongly oxidised plutons tend to have higher concentrations of LREE relative to MREE. Manganese concentrations are higher in apatite from reduced granitoids because Mn2+ substitutes directly for Ca2+. The La/Ce ratio of apatite is wellcorrelated with the whole-rock K2O and Na2O contents, as well as with the oxidation state and ASI. 
Because apatite trace-element composition reflects the chemistry of the whole rock, it can be a useful indicator mineral for the recognition of mineralised granite suites, where particular mineralisation styles are associated with granitoids that have specific geochemical fingerprints." name="eprints.abstract" />
<meta content="2001-08" name="eprints.date" />
<meta content="published" name="eprints.date_type" />
<meta content="Australian Journal of Earth Sciences" name="eprints.publication" />
<meta content="48" name="eprints.volume" />
<meta content="4" name="eprints.number" />
<meta content="603-619" name="eprints.pagerange" />
<meta content="10.1046/j.1440-0952.2001.00879.x" name="eprints.id_number" />
<meta content="UNSPECIFIED" name="eprints.thesis_type" />
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<meta content="0812-0099" name="eprints.issn" />
<meta content="http://dx.doi.org/10.1046/j.1440-0952.2001.00879.x" name="eprints.official_url" />
<meta content="AYERS J. C. &amp; WATSON E. B. 1993. Apatite/fluid partitioning of rare earth elements and strontium: Experimental results at 1.0 GPa and 1000 degrees C and application to models of fluid-rock interaction. Chemical Geology 110, 299-314.
BLAKE D. H., ETHERIDGE M. A., PAGE R.W., STEWART A. J.,WILLIAMS P. R. &amp; WYBORN L. A. I. 1990. Mount Isa Inlier-regional geology and mineralisation. In: Berkman D. A. &amp; Mackenzie D. H. eds. Geology of Australian and Papua New Guinean Mineral Deposits, pp. 915-925. Australasian Institute of Mining and Metallurgy, Melbourne.
BLEVIN P. L. &amp; CHAPPELL B.W. 1995. Chemistry, origin and evolution of mineralised granites in the Lachlan Fold Belt, Australia: the metallogeny of I- and S-type granites. Economic Geology 90, 1604-1619.
BUDZINSKI H. &amp; TISCHENDORF G. 1989. Distribution of REE among minerals in the Hercynian postkinematic granites of
Westerzgebirge-Vogland, GDR. Zeitschrift Fur Geologische
Wissenschaften 17, 1019-1031.
CASILLAS R.,NAGY G., PANTO G., BRANDLE J. &amp; FORIZS I. 1995. Occurrence of Th, U, Y, Zr, and REE-bearing accessory minerals in late-Variscan granitic rocks from the Sierra de Guadarrama (Spain). European Journal of Mineralogy 7, 989-1006.
CHAPPELL B. W. &amp; WHITE A. J. R. 1992. I- and S-type granites in the Lachlan Fold Belt. Transactions of the Royal Society of Edinburgh: Earth Science 83, 1-26.
EVANS O. C. &amp; HANSON G. N. 1993. Accessory-mineral fractionation of rare-earth element (REE) abundances in granitoid rocks. Chemical Geology 110, 69-93.
EXLEY R. A. 1980. Microprobe study of REE-rich accessory minerals: implications for Skye granite petrogenesis and REE mobility in hydrothermal systems. Earth and Planetary Science Letters 48, 97-110.
FLEET M. E. &amp; PAN Y. 1995. Site preference of rare earth elements in fluorapatite. American Mineralogist 80, 329-335.
HAZELL M., KILGOUR B., WYBORN L. A. I., SHERATON J. W. &amp; RYBURN R. 1995. ROCKCHEM dataset, Version 2 Documentation. Australian Geological Survey Organisation Record 1995/26.
HUGHES J. M., CAMERON M. &amp; CROWLEY K. D. 1991. Ordering of divalent cations in the apatite structure: crystal structure refinements of natural Mn- and Sr-bearing apatite. American Mineralogist 76, 1857-1862.
MARSHALL D. J. 1988. Cathodoluminescence of Geological Materials. Unwin Hyman, Boston.
NASH W. P. 1984. Phosphate minerals in terrestrial igneous and metamorphic rocks. In: Nriagu J. O. &amp; Moore P. B. eds. Phosphate Minerals, pp. 215-241. Springer-Verlag, Berlin.
NORMAN M. D., PEARSON N. J., SHARMA A. &amp; GRIFFIN W. L. 1996.
Quantitative analysis of trace elements in geological materials by laser ablation ICPMS: instrumental operating conditions and calibration values of NIST glasses. Geostandards Newsletter 20, 247-261.
OREILLY S. Y., GRIFFIN W. L. &amp; RYAN C. G. 1991. Residence of trace elements in metasomatized spinel lherzolite xenoliths: a protonmicroprobe study. Contributions to Mineralogy and Petrology 109, 98-113.
ROEDER P. L., MACARTHUR D., XIN-PEI M. A., PALMER G. R. &amp;
MARIANO A. N. 1987. Cathodoluminescence and microprobe study
of rare earth elements in apatite. American Mineralogist 72,
801-811.
RONSBO J. G. 1989. Coupled substitutions involving REEs and Na and Si in apatites in alkaline rocks from the Ilimaussaq intrusion, South Greenland, and the petrological implications. American Mineralogist 74, 896-901.
RYAN A. J. 1998. Ernest Henry copper-gold deposit. In: Berkman D. A. &amp; Mackenzie D. H. eds. Geology of Australian and Papua New Guinean Mineral Deposits, pp. 759-768. Australasian Institute of Mining and Metallurgy, Melbourne.
SHANNON R. D. 1976. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallographica A32, 751-767.
SHNUKOV S. E., CHEBURKIN A. K. &amp; ANDREEV A. V. 1989. Geochemistry of wide-spread coexisting accessory minerals and their role in investigation of endogenetic and exogenetic processes. Geological Journal 2, 107-114 (in Russian). 
WATSON E. B. &amp; GREEN T. H. 1981. Apatite/liquid partition coefficients for the rare earth elements and strontium. Earth and Planetary Science Letters 56, 405-421.
WILLIAMS P. J. (Editor) 1998a. A Special Issue Devoted to Metallogeny of the McArthur River Mount Isa Cloncurry Minerals Province Economic Geology 93(8).
WILLIAMS P. J. 1998b. An introduction to the metallogeny of the McArthur River Mount Isa Cloncurry Province. Economic
Geology 93, 1120-1131. 
WYBORN L. A. I. 1998. Younger ca 1500 Ma granites of the Williams and Naraku Batholiths, Cloncurry district, eastern Mt Isa Inlier: geochemistry, origin, metallogenic significance and exploration indicators. Australian Journal of Earth Sciences 45, 397-411.
WYBORN L. A. I. &amp; PAGE R. W. 1983. The Proterozoic Kalkadoon and Ewen batholiths, Mount Isa Inlier, Queensland: source, chemistry, age and metamorphism. BMR Journal of Australian Geology &amp; Geophysics 8, 53-69.
WYBORN L. A. I., PAGE R. W. &amp; MCCULLOCH M. T. 1988. Petrology, geochronology and isotope chemistry of the post-1820 Ma granites of the Mount Isa Inlier: mechanisms for the generation of Proterozoic anorogenic granites. Precambrian Research 40/41, 509-541.
WYBORN L. A. I., WYBORN D., WARREN R. G. &amp; DRUMMOND B. J. 1992. Proterozoic granite types in Australia: implications for lower crust composition, structure and evolution. Transactions of the Royal Society of Edinburgh: Earth Sciences 83, 201-209." name="eprints.referencetext" />
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<meta content="The concentrations of trace elements in apatite from granitoid rocks of the Mt Isa Inlier have been investigated using the laser-ablation inductively coupled plasma-mass spectrometry (ICP-MS) microprobe.
The results indicate that the distribution of trace elements [especially rare-earth elements (REE), Sr, Y, Mn and Th] in apatite strongly reflects the chemical characteristics of the parental rock. The variations in the trace-element concentrations of apatite are correlated with parameters such as the SiO2 content, oxidation state of iron, total alkalis and the aluminium saturation index (ASI). The relative enrichment of Y, HREE and Mn and the relative depletion of Sr in the apatites studied reflect
the degree of fractionation of the host granite. Apatites from strongly oxidised plutons tend to have higher concentrations of LREE relative to MREE. Manganese concentrations are higher in apatite from reduced granitoids because Mn2+ substitutes directly for Ca2+. The La/Ce ratio of apatite is wellcorrelated with the whole-rock K2O and Na2O contents, as well as with the oxidation state and ASI. 
Because apatite trace-element composition reflects the chemistry of the whole rock, it can be a useful indicator mineral for the recognition of mineralised granite suites, where particular mineralisation styles are associated with granitoids that have specific geochemical fingerprints." name="DC.description" />
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    <h1 class="ep_tm_pagetitle">Trace-element signatures of apatites in granitoids from the Mt Isa Inlier, northwestern Queensland</h1>
    <p style="margin-bottom: 1em" class="not_ep_block"><span class="person_name">Belousova, E.A.</span> and <span class="person_name">Walters, S.G.</span> and <span class="person_name">Griffin, W.L.</span> and <span class="person_name">O'Reilly, S.Y.</span> (2001) <xhtml:em>Trace-element signatures of apatites in granitoids from the Mt Isa Inlier, northwestern Queensland.</xhtml:em> Australian Journal of Earth Sciences, 48 (4). pp. 603-619. ISSN 0812-0099</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a href="http://eprints.utas.edu.au/1964/1/Belousova%2C_Walters_et_al_2001.pdf"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" border="0" class="ep_doc_icon" /></a></td><td valign="top"><a href="http://eprints.utas.edu.au/1964/1/Belousova%2C_Walters_et_al_2001.pdf"><span class="ep_document_citation">PDF</span></a> - Full text restricted - Requires a PDF viewer<br />734Kb</td><td><form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/request_doc"><input value="2444" name="docid" accept-charset="utf-8" type="hidden" /><div class=""><input value="Request a copy" name="_action_null" class="ep_form_action_button" onclick="return EPJS_button_pushed( '_action_null' )" type="submit" /> </div></form></td></tr></table><p style="margin-bottom: 1em" class="not_ep_block">Official URL: <a href="http://dx.doi.org/10.1046/j.1440-0952.2001.00879.x">http://dx.doi.org/10.1046/j.1440-0952.2001.00879.x</a></p><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">The concentrations of trace elements in apatite from granitoid rocks of the Mt Isa Inlier have been investigated using the laser-ablation inductively coupled plasma-mass spectrometry (ICP-MS) microprobe.&#13;
The results indicate that the distribution of trace elements [especially rare-earth elements (REE), Sr, Y, Mn and Th] in apatite strongly reflects the chemical characteristics of the parental rock. The variations in the trace-element concentrations of apatite are correlated with parameters such as the SiO2 content, oxidation state of iron, total alkalis and the aluminium saturation index (ASI). The relative enrichment of Y, HREE and Mn and the relative depletion of Sr in the apatites studied reflect&#13;
the degree of fractionation of the host granite. Apatites from strongly oxidised plutons tend to have higher concentrations of LREE relative to MREE. Manganese concentrations are higher in apatite from reduced granitoids because Mn2+ substitutes directly for Ca2+. The La/Ce ratio of apatite is wellcorrelated with the whole-rock K2O and Na2O contents, as well as with the oxidation state and ASI. &#13;
Because apatite trace-element composition reflects the chemistry of the whole rock, it can be a useful indicator mineral for the recognition of mineralised granite suites, where particular mineralisation styles are associated with granitoids that have specific geochemical fingerprints.</p></div><table style="margin-bottom: 1em" border="0" cellpadding="3" class="not_ep_block"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Article</td></tr><tr><th valign="top" class="ep_row">Keywords:</th><td valign="top" class="ep_row">apatite, granitoid, indicator minerals, mineralisation, Mt Isa Inlier, trace elements.</td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/260100.html">260000 Earth Sciences &gt; 260100 Geology</a></td></tr><tr><th valign="top" class="ep_row">Collections:</th><td valign="top" class="ep_row">UNSPECIFIED</td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">1964</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">Mrs Katrina Keep</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">19 Sep 2007</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">30 Jan 2008 16:16</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=1964;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&amp;eprintid=1964">item control page</a></p>
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